Study on the mechanism of the influence of flood storage at the end of the Three Gorges Reservoir on the phosphorus forms in the sediments of the tributary reservoir bay

Abstract

This paper studies the influence of the impounding process during flood recession in the TGR on the distribution and rerelease of sediment phosphorus forms in the Xiangxi Bay in 2016. Influenced by the main stream of the Three Gorges Reservoir (TGR) flowing backward during impoundment, the water environmental conditions, sediment grain size and sediment-forming environment of the tributary bays change correspondingly. In this study, it is found that the water temperature (WT), turbidity and oxidation–reduction potential (ORP) of the overlying water in the Xiangxi Bay decrease, while the pH increases after impoundment in the TGR. The backward flow of the main stream containing a large amount of sediments increases the sediment content of the tributary bay, and the difference in sediment particle size between the main stream and tributaries narrows after resedimentation. The phosphorus adsorbed on the sediments increases the total phosphorus (TP) in the sediments of the Xiangxi River to 1.3 times its value before water impoundment. NaOH-P and HCl-P in the Xiangxi River sediments account for 42% and 38% of the TP, respectively, and the contents of the various phosphorus forms are ranked in the following order: NaOH-P > HCl-P > organic phosphorus (OP). After impoundment, HCl-P accounts for 67% of the TP, and the relative contents of the phosphorus forms are ranked as: HCl-P > OP > NaOH-P. Orthophosphate (PO43−-P) in the Xiangxi sediments before and after impoundment acts as a source, and the PO43−-P diffusion flux increases from approximately − 0.0029 to 0.0059 mg (m2 d)−1 before impoundment to 0.0067–0.1071 mg (m2 d)−1 after impoundment, which is mainly due to the increased difference in concentration of PO43−-P [ρ(PO43−-P)] between the sediment interstitial water and overlying water after impoundment. After nutrient recharge of the main stream of the Yangtze River, ρ(PO43−-P) of the overlying water is 3.7 times its value before impoundment, and after the release of NaOH-P in the sediments, ρ(PO43−-P) of the interstitial water is 8.3 times its value before water impoundment. Hence, the risk of nutrient release from the sediments in the Xiangxi Bay increases.