Study on the Feasibility of Plasma (DBD Reactor) Cracking of Different Hydrocarbons (<inline-formula> <tex-math notation="TeX">\(n\) </tex-math></inline-formula>-Hexadecane, Lubricating Oil, and Heavy Oil)

Abstract

In this paper, the cracking ability of plasma in the oil refinery, as a novel study, has been discussed. Furthermore, the cracking of n-hexadecane, lubricating oil, and heavy oil by a nonthermal plasma reactor was studied to investigate the liquid and gaseous products, gas chromatography, and simulated distillation (Sim Dis) analyzer were used. The results showed the production of hydrogen, ethane, ethylene, propane, propylene, and other hydrocarbons as a result of feedstock cracking. In these experiments, both lighter and heavier hydrocarbons were produced. In the first part, the n-hexadecane (C <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">16</sub> H <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">34</sub> ) was injected to the reactor. The production rate of hydrogen, ethylene, and propylene were 12.74, 6.91, and 2.32 sccm, respectively. In the second part, lubricating oil, containing heavier hydrocarbons (C <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">13</sub> -C <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">42</sub> ), was chosen as a feed. Plasma was able to crack this feed to C <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">4</sub> -C <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">12</sub> with 39.77% (weight percent). In this part, the weight percent of C <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">17+</sub> (heavy hydrocarbons) decreased from 93.0% to 40.19%, showing that 56.8% of the heavy fraction of lubricating oil was cracked to lighter hydrocarbons. Finally, heavy oil was injected to the reactor and Sim Dis data showed that 95% of eluted materials were taken at 628°C and 459°C temperatures for raw and plasma treated heavy oils, showing 169°C difference in the distribution of the boiling point of samples. This difference was due to the presence of lighter hydrocarbons with lower boiling point.