Study on the Electrical Conductivity of Inorganic Conductive Network in Sediments

Abstract

The inorganic conductive network provides an essential channel for electron transport and supports the biogeochemical process in sediments, but the conductive mechanism of conductive network is not well understood. In this work, theory of circuit and electronics was applied to build a three-dimensional (3D) resistivity network simulation model for exploring the conductive mechanism and analysing the effect of the particle size on the conductive characteristic of inorganic conductive network. In order to simulate the real sediment environment, inorganic composites with silica (SiO2) particles as matrix using magnetite (Fe3O4) particles as fillers are constructed. The simulation results reveal that the electrical conductivity of these composites rises nonlinearly with the increasing volume fraction of conductive fillers, which is consistent with the percolation theory. Moreover, small-sized conductive particles or large-sized matrix particles are confirmed to exert a positive part in enhancing electrical conductivity of composites.