Abstract
The current study presents research into the effect of graphene oxide (GO) with a carbon to oxygen ratio of 4:1 on the fluidity, hydration, microstructure, mechanical and physical properties of Portland cement pastes and mortars. The amounts of GO investigated were 0.02%, 0.04%, and 0.06% by weight of cement, while for mortars, an extra composition with 0.1% was also prepared. According to the results, the fluidity of cement paste and mortar increased and the hydration process was slightly retarded with the addition of GO. Despite this, improvements in compressive and flexural strength were established in the mortars containing GO. The maximum effects (~22% and ~6%, respectively) were obtained with the addition of 0.06% GO. The calculation of estimated strength proportional to samples of equal density showed that for mortars cured for 7 days the gain in strength was directly related to the gain in density. For mortar samples cured for 28 days, the estimated strength was found to be significantly higher than that of the reference sample, indicating that besides density there are other factors determining the improvement in strength of mortars modified with GO. The possible structure strengthening mechanisms are discussed.
Highlights
Cement is a widely used binding material in construction
The current study focused on the investigation of the properties of cement pastes and mortars modified with low oxidized graphene oxide (GO), in which the C to O ratio is around 4
The results of X-ray microanalysis by energy dispersive spectrometer (EDS) showed that GO consisted of ~77 wt.% C and
Summary
Cement is a widely used binding material in construction. The use of cement in the production of concretes and mortars for a large number of applications has made it a very important material in civil engineering. Cementitious materials are typically characterized as brittle materials having low tensile strength [1]. Recent developments in nanotechnology have made it possible to produce nanosized materials in the form of fibres/particles (e.g., nano-silica and carbon nanotubes) that could be used as reinforcements to prevent the microcrack initiation, and their further growth, at the outset. Nano-reinforcements can control cracks at the nano scale, i.e., before they develop into micro-size cracks; in cementitious materials, they are more effective than conventional millimetre-sized reinforcements such as steel bar/fibre [2].
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.