Study on the characteristics of matrix compressibility and its influence factors for different rank coals∗

Abstract

To thoroughly understand the mechanism of permeability change and improve production in coalbed methane development, it is important to clarify the evolution characteristics and influencing factors of matrix compressibility for various coal ranks. This paper presents calculations of matrix compressibility coefficients of different rank coals through mercury intrusion porosimetry (MIP) and N2 adsorption. Furthermore, the evolution of coal material and pores based on coal rank is analyzed to study their effect on matrix compressibility coefficients. The results show that the relationship between matrix compressibility coefficients and coal rank is a cubic polynomial function, in which two inflection points are situated in the maximum vitrinite reflectance (Ro,max) = 1.3% and 2.5%. For coals with Ro,max < 1.3%, matrix compressibility coefficients increase as vitrinite and volatile matter contents increase, which may be related to the lower microhardness of vitrinite and the more random structure of aromatic carbon micells surrounded or linked by carbon functional groups, such as aliphatic chains, methoxyl and carboxylic functional groups. Moreover, the regular change of moisture content with coal rank is similar to matrix compressibility coefficients and it also plays a positive role in matrix compressibility. However, the inertinite and mineral content has a rather opposite effect on matrix compressibility. For the pore structure, the larger porosity and micropore volume in coals, the greater matrix compressibility. The coals Ro,max < 1.0%, which have a loose chemical structure and high micropore volume, can bear a greater intrusion pressure than the coals with Ro,max > 1.0%, in which the micropore structure will be broken when pressure exceeds 150 MPa. The coals with greater fractal dimension are more sensitive to stress. The matrix compression can lead to reduction of micropore volume and can make the micropore structure more irregular. It indicates that the increasing of effective stress with gas discharge could reduce the permeability of the reservoir and enhance the adsorption of micropore.