Abstract

This paper presents an experimental study of spray characterization of MD-NH (a blend of methyl decanoate and n-heptane in a molar ratio of 1:1 to characterize biodiesel) in an in-cylinder environment of diesel engines to provide a reference for the experimental study of engines in advanced combustion mode. Based on the Peng-Robinson state equation, the thermodynamic model of real fluid was established, and the influence law of ambient temperature and pressure on the diffusion characteristics of fuel flow was analyzed. Based on the constant volume combustion bomb experiments, the variations of spray penetration distance, spray cone angle, spray projection area, spray air entrainment mass, and spray fragmentation forms in different critical environment conditions were studied. The results show that the transport properties of the fuel change abruptly within the critical point neighborhood of the fuel. As the ambient temperature increases, near the critical temperature, the thermal conductivity of biodiesel decreases and then increases; density and kinematic viscosity decrease at an accelerated rate; and surface tension increases to a maximum and then disappears sharply. The diffusion coefficient decreases sharply when the ambient pressure reaches the critical pressure. The spray characteristics of biodiesel in sub/supercritical conditions were different. Compared with the subcritical environment, the biodiesel spray penetration distance decreases, the spray cone angle increases, the spray projection area decreases, and the air entrainment mass increases in the supercritical atmosphere, which induces a gas-liquid interface mixing layer and promotes the mixing of biodiesel with the atmosphere gas. The experimental data in this paper fill the gap in the study of biodiesel spray characteristics in supercritical environments and provide a basis for high-fidelity numerical simulation of the spray model.

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