Abstract
The disproportionation reaction of aluminium and its halides is studied by means of a differential thermal analysis at reduced pressure, and the temperature ranging from 1, 250°K to 1, 330°K. The reaction proceed through the formation of aluminium monofluoride by the direct liquid aluminium and solid aluminium trifluoride reaction.The aluminium monofluoride pressure versurs temperature are determined by the following equation:2Al(l)+AlF3(s)=3AlF(g)logp(mmHg)=-11, 270/T+10.267.Thermodynamic consideration is also attempted with respect to the above reaction.
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