Study on performance and water deactivation mechanism of low-temperature denitrification catalyst in high-humidity flue gas

Abstract

To address water poisoning issues of Selective Catalytic Reduction (SCR) denitrification catalysts in high-humidity flue gas, this study synthesized catalysts including Co–Mn/TiO2, Co–Mn–Ce/TiO2, Co–Mn–Ce/TiO2–Si, and Co–Mn–Ce/TiO2 (stearic acid). The activity of the catalysts at low temperatures and high humidity (140–180 °C, 0–35 vol%) was evaluated. Furthermore, the characterization of the most effective of these (the Co–Mn–Ce/TiO2 (stearic acid) catalyst) was performed. The results revealed distinct mechanisms of water poisoning under high- and low-humidity conditions. Under high humidity, the dissolution of water molecules affected the catalyst structure and thereby, resulted in reduced dispersibility of the active components. Conversely, at low humidity, the dissolution effect was relatively marginal, which resulted in a more stable catalyst structure. High-humidity flue gas reduced the catalyst acidity and thereby, hindered NH3 adsorption. Meanwhile, low-humidity flue gas had a lesser impact on the catalyst. High-humidity flue gas hinders the conversion of Co ions in Co–Mn–Ce/TiO2（stearic acid ) to higher oxidation states and reduced Ce4+ to Ce3+. This resulted in decreased Mn4+ on the catalyst surface and reduced chemisorbed oxygen (Oa). This, in turn, affected the adsorption and storage of oxygen by the catalyst.