Abstract

In this study, based on the sensitivity of the chemical composition fluctuation to the thermodynamic parameter, which controls the level of the stacking fault energy (SFE), a series of high Cr–Mn–N twinning-induced plasticity (TWIP) stainless steels are designed by using a sublattice model, and their mechanical properties and micro deformation mechanism are analyzed The formation of mechanical twins (Mts) during the deformation makes the test steel show a perfect combination of strength and ductility after different solution treatments. Among them, after a solution treatment at 950 °C and 1050 °C, the 19Cr–0.7N and 19CrSi–0.7N samples have the maximum value with the product of the strength and plasticity reaching 60.7% and 64.6%, and 12Cr–CN has the maximum value after the solution treatment at 1200 °C, reaching 81.3%. The SFE values of the 19Cr–0.7N and 19CrSi–0.7N samples were relatively high, 48 mJ·m−2 and 45 mJ·m−2, respectively. The SFE of 12Cr–CN is 37 mJ·m−2, and the Mts grow rapidly during the deformation and maintain the highest twinning density under the same strain conditions. The characterization of the tensile samples occurs under different deformations by electron backscattered diffraction (EBSD) and transmission electron microscope (TEM). The results of the EBSD local misorientation difference angle analysis showed the Silicon element addition with a good Mts saturation rate. It is observed from the TEM that the nucleation process of the Mts with a high SFE is difficult, and the Mts emit and grow inward along the grain boundary during the tensile process and present a cross shape with the increase in strain. The contribution of the grain boundary strengthening (σ0), dislocation strengthening (σf), and twinning strengthening effect (σt) under dynamic micro-refinement to stress were calculated. It is known that under a certain amount of strain, the ratio of σt and σf changes with increasing, and when the contribution of the twinning deformation to the stress exceeds about 25%, the reinforcement of the plastic deformation is dominated by the plane of σf.

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