Abstract

In order to solve the frosting problem of air source heat pump (ASHP) outdoor heat exchange under low-temperature and low-humidity conditions, a superhydrophobic aluminum (Al) surface with a contact angle (CA) of 158.3° was prepared by chemical etching. The microscopic characteristics of droplet condensation and the freezing process of a superhydrophobic surface were revealed through visual experiments and theoretical analysis. On this basis, the frost-suppression effect of a superhydrophobic Al-based surface simulating the distribution of actual heat exchanger fins was preliminarily explored. The results demonstrated that, due to the large nucleation energy barrier and the coalescence-bounce behavior of droplets, the condensed droplets on the superhydrophobic surface appeared late and their quantity was low. The thermal conductivity of the droplets on a superhydrophobic surface was large, so their freezing rate was low. The frosting amount on the superhydrophobic Al-based surface was 69.79% of that of the bare Al-based surface. In turn, the time required for melting the frost layer on the superhydrophobic Al-based surface was 64% of that on the bare Al-based surface. The results of this study lay an experimental and theoretical foundation for the application of superhydrophobic technology on the scale of heat exchangers.

Highlights

  • Electric air source heat pump (ASHP) have found worldwide applications due to their advantages of energy saving and environmental protection [1,2,3]

  • In order to clarify the effect of chemical etching on the contact angle (CA) and hydrophobic proper‐

  • Inlayer order to clarify the effect ofafter chemical etching on specimens the CA andafter hydrophobic proper‐

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Summary

Introduction

Electric ASHPs have found worldwide applications due to their advantages of energy saving and environmental protection [1,2,3]. When the heat pump operates under heating conditions in winter, at ambient air temperatures of −15 ◦ C to 11.5 ◦ C and relative humidity higher than 30%, coil pipes of heat pump outdoor units are prone to frosting [4]. In order to ensure the operation efficiency of ASHPs in winter, a variety of methods have been proposed to restrain and defrost the frost layer on the coil surface. Used defrosting techniques include electric heating defrosting [7,8], reverse-cycle defrosting [9,10], thermal storage defrosting [9,10], and hot-gas bypass defrosting [10,11,12,13].

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