Abstract

The gel system used in the preparation of dispersed particle gel for water shutoff treatments, which is composed of polyacrylamides and zirconium acetate, was investigated. The gelation process, the effects of various parameters on the gelation properties, the thermal stability, and the microstructure were addressed. The cross-linking reaction process is divided into three successive steps: induction, rapid cross-linking, and stabilization. High polymer and crosslinker concentrations reduce gelation time and increase gel strength. In addition, adding salts to the brine or increasing the temperature also decrease gelation time and increase gel strength. The optimum pH for the gel system is 7.49. In field applications, this gel system is recommended to be used within 130 °C using differential scanning calorimetry. The gel formed in a three-dimensional network structure was confirmed through environmental scanning electron microscopy.

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