Abstract
AbstractThe copolymerization of styrene with maleic anhydride (MAh) in the presence of 1‐(ethoxycarbonyl)prop‐1‐yl dithiobenzoate was carried out under UV irradiation at room temperature, and showed ‘living’ polymerization nature which was evidenced by: linear evolution of molecular weight with conversion; and narrow molecular weight distribution (Mw/Mn = 1.08–1.20). The compositional analysis and the sequence structural information of the copolymer obtained from Distortionless Enhancement by Polarization Transfer (DEPT) NMR experiments demonstrated that the copolymers obtained possess strictly alternating structure.© 2003 Society of Chemical Industry
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