Study on CO2* chemiluminescence of CH4/O2 co-flow diffusion flame based on the chemical kinetic mechanism

Abstract

Chemiluminescence of CO2* is suitable for characterizing flame properties such as flame structure, equivalence ratio and heat release rate. However, experimental studies and numerical simulations of CO2* are not yet complete. In this work, the two-dimensional distributions of CO2* chemiluminescence were obtained by a high-resolution CCD camera. Numerical simulation results of CO2* were performed based on the detailed reaction kinetics mechanism of CO2* and were in good agreement with that of experiments. The differences of CO2* reactions at different axial positions were studied. The main CO2* formation reaction R2(CH + O2 = CO2*+H) at the burner outlet and R1(O + CO + M = CO2*+M) at the core reaction zone were determined. On the fuel side, the R1 reaction rate was mainly affected by temperature. On the oxidizer side, the R1 reaction rate was affected by temperature and reactant mole fraction. The main quenching reaction was R5(CO2*+H2O = CO2 + H2O). The oxygen-fuel equivalence ratio changed the reaction rate of formation and quenching reactions mainly by affecting temperature and reactant mole fraction.