Study on characteristics of organic components in condensable particulate matter before and after wet flue gas desulfurization system of coal-fired power plants

Abstract

Wet flue gas desulfurization (WFGD) in coal-fired power plants has a great impact on the emission of particulate matter, including filterable particulate matter (FPM) and condensable particulate matter (CPM). In this paper, CPM and FPM in flue gas before and after WFGD in coal-fired power plants were sampled in parallel. FPM was tested according to ISO standard 23210–2009, and CPM was tested according to U.S. EPA Method 202. A method for quantitatively analyzing fatty acid methyl esters in CPM was established, and the removal capacity of fatty acid methyl esters and phthalate esters by WFGD in a typical coal-fired unit was compared. Results show that WFGD has a significant effect on particle size distribution, concentration, and chemical composition. WFGD has a high removal efficiency of inorganic components in CPM, up to 54.74%. CPM contains a variety of organic compounds, including hydrocarbons, esters, siloxanes, halogenated hydrocarbons, and so on. In particular, esters are an important component in CPM, whose concentration tends to decrease after WFGD. Furthermore, a total of 11 fatty acid methyl esters and 5 phthalate esters were detected in CPM before and after WFGD. Noted that fatty acid methyl esters account for 13.38% of CPM, which make a higher contribution to the concentration of particulate matter than phthalate esters, while WFGD has a stronger control effect on the removal of phthalates.