Abstract

We report on the dry etch process parameters and the associated etch rates for target and mask materials, as well as surface roughness in an inductively coupled plasma (ICP) for the (AlGaIn)(AsSb)-compounds. The essential chemistry is based on Cl2 with the addition of N2 for sidewall passivation. The optimized ICP etch process is capable of producing high aspect ratio structures with smooth sidewalls. In situ reflectance monitoring with a 670-nm-wavelength laser was used to enable stop-etching at a material interface with high accuracy. Given the additional need for highly selective wet chemical etchants in the fabrication of GaSb based electronic and optoelectronic devices, an extensive investigation was also performed to examine numerous etch solutions. These etchants were listed with etch rates, selectivities, and surface roughness in order to validate their suitability for intended applications. Despite the frequent use of GaSb or InAsSb materials for etch stop layers against each other, devices where their unique type-II broken bandgap alignment is undesired require new selective wet etchants between GaSb and AlGaAsSb with good selectivity. All of the wet chemical and dry etching processes described here were optimized using an n-type GaSb substrate.

Highlights

  • Dry and wet etch processes are important and widely used for the fabrication of electronic and optoelectronic devices

  • It is observed that hydrofluoric acid (HF) etches plasma-exposed antimonides unlike other III-Vs

  • Lasers, leading to photonic ICs (PICs) where active and passive regions are defined by selective wet chemical etching, multi-quantum well (MQW) regions are selectively removed from the top of the waveguide layer, defining low-loss passive waveguides [9]

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Summary

Introduction

Dry and wet etch processes are important and widely used for the fabrication of electronic and optoelectronic devices. For fabricating many optoelectronic devices including widelytunable lasers, e.g. sampled-grating distributed-Bragg-reflector (SG-DBR) [7] and verticalcavity surface-emitting lasers (VCSELs) [8], one usually uses etch-stop layers in order to control the etch depth with high accuracy of nanometer order. In such a way, it is possible to selectively remove the desired materials against another layer. Lasers, leading to photonic ICs (PICs) where active and passive regions are defined by selective wet chemical etching, multi-quantum well (MQW) regions are selectively removed from the top of the waveguide layer, defining low-loss passive waveguides [9]. The comprehensive detailing on the selective dry and wet etching for antimonides and its alloys will be beneficial for the fabrication of next-generation high-quality optoelectronic and electronic devices

Sample preparation
Preparation of etch solutions
Etch reactor with etch depth monitor
Dry etching
Wet chemical etching
Buffered HF
Findings
Conclusion
Full Text
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