Abstract
Thermal analysis shows that the interaction of boric acid with pentaerythritol on heating leads to the formation of a polymeric complex acid (1∶1) and the direction of the interaction does not depend on the molar ratio of the reacting compounds. The interaction of boric acid with methriol and ethriol leads to the formation of two types of esters, depending on the molar ratio of the reactants. The formation of an unstable polyolboric acid is an intermediate stage of each interaction.
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