Abstract

Various chemicals are used for protecting wood samples against fungi, and some of them are released in water, leading to pollution of the water. The kinetics of release of pentachlorophenol in water has here been studied, by considering the diffusion through the wood along the three principal axes of diffusion. The experiments and the modelling of the process is successfully coupled. The numerical model takes the three principal diffusivities, the partition factor, the volumes of wood and water into account. The effect of the length of the wood sample taken along the longitudinal axis of diffusion is especially studied, as the longitudinal diffusivity is much higher than the other two principal diffusivities. The effect of the relative volumes of wood and water is also of considerable interest not only for the concentration of the chemical in water but also for the rate of release.

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