Abstract
The products of the reaction of pyridinium poly(hydrogen fluoride), PPHF, with KIO 3, Na 2SnO 3, NaBiO 3, K 2CrO 4, Na 2MoO 4 and Na 2WO 4 were KIO 2F 2; Na 2SnF 6; NaHF 2, BiF 3; K 3CrF 6, KHF 2, (PyH) 3CrF 6; NaHF 2, (PyH) 2MoO 2F 4·2NaHF 2; and (PyH) 2WO 2F 4·2NaHF 2, respectively, while KClO 3, KBrO 3 and KIO 4 react with complete decomposition to form KHF 2 as the fluorinated product. This differential reactivity and mode of reaction has been discussed in terms of the oxidation state of the central atom, the nature and strength of the bonds and the complex behaviour of the formed intermediate or fluorinated products that undergo complexation or solvation with pyridine and/or hydrogen fluoride.
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