Abstract
Variations of the equilibrium constant K′ = [Pb(II)] · [Cl 2]/[Pb(IV)] have been studied in dependence on the acidity of the solution, based on the polarographic behavior and determination of the concentration of tetravalent lead in the presence of chlorine. A possible scheme of the equilibrium is discussed, based on the invariance of this constant in the range of 2 to 4.5 M HCl and comparison with literature data.
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