Abstract
Data on glass formation, crystallization, and physicochemical properties in the binary (Bi2O3-B2O3) and ternary (PbO-Bi2O3-B2O3, ZnO-Bi2O3-B2O3, and BaO-Bi2O3-B2O3) systems are presented. The feasibility of glasses with high bismuth oxide content (>80 mol %) is addressed. The formation of a glass network of octahedral [BiO6] structural units rather than [BiO3] ones in such systems is shown.
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