Abstract
A successful preparation of a Schiff base copper complex was carried out directly in rap oil, using a W/O microemulsion reactor. The prepared Schiff base copper complex dispersed equably and spontaneously in the oil. Owing to a modification of the rap oil, by addition of 2%wt of Cu (II) chelate of bissalicylaldehyde-ethylenediamine, the friction coefficient decreased by 80% compared to that of the original one. It was verified by energy dispersive spectroscopy (EDS) and x-ray photoelectron spectroscopy (XPS) analyses that steel/steel rubbing pairs underwent a selective transferring process with such modified lubricants. It was suggested that the mechanism for the improvement in the tribological characteristics of the modified lubricants was due to a selective transferring effect. The Cu (II) chelate of bissalicylaldehyde-ethylenediamine not only served as an additive in the rap oil, but also self-assembled on the surface of the 100Cr6 steel. The self-assembled monolayer (SAM) was examined using SEM techniques. The SAM was characterized with cyclic voltammetry (CV). It indicated that the SAM could activate the rubbing surface of 100Cr6 steel, which benefited the tribological chemical reaction.
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