Abstract

The stepwise nucleophilic addition of 2-mercaptoethanol ( 2) to 1-fluoroalkyl-2-iodo-alkenes ( 1) was studied. Fluorine-containing building blocks of a new type ( 4) containing a fluorine atom, a fluoroalkyl-substituted double bond and a latent carbonyl group were synthesized in good yield via the intermediate thioethers 3. A reasonable pathway is suggested.

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