Abstract
Carbon-13 NMR spectra have been obtained for $p$-methoxy benzylidene ${p}^{\ensuremath{'}}\ensuremath{-}n$-butylaniline (MBBA) in the isotropic, nematic, and solid phases. Sharp, resolved spectra were obtained in the nematic phase with high-power proton-spin decoupling. The isotropic-nematic transition is accompanied by a discontinuous change in $^{13}\mathrm{C}$ absorption frequencies due to the molecular ordering and anisotropic chemical shielding. It is concluded that the benzene rings reorient rapidly about the para axes. Employing average values from studies of $^{13}\mathrm{C}$ chemical shielding tensors in model aromatic solids, absolute values of the order parameter $S$ are estimated and normalized values are compared with previous results. The nematic-solid transition is accompanied by sudden and severe line broadening due to anisotropic chemical shielding.
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