Abstract
Silicon-nitride films with silicon nanoparticles have been prepared at 300 °C by remote plasma-enhanced chemical vapor deposition using mixtures of H 2, Ar and SiH 2Cl 2 and various NH 3 flow rates. The films were characterized by means of Rutherford backscattering spectrometry, Fourier-transform infrared spectroscopy, single wavelength ellipsometry, high-resolution transmission electronic microscopy, atomic force microscopy and photoluminescence measurements. It was found a chemical stability as well as an increase in the photoluminescence signal for those films with the greatest amount of NH 3. The increase in the photoluminescence signal is due to a quantum confinement effect produced by the nanoparticles, which were formed during the film's preparation process.
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More From: Physica E: Low-dimensional Systems and Nanostructures
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