Abstract
The densities of 1,3‐butanediol‐water mixtures and some tetraalkylammonium iodide salt solutions in these solvent mixtures at different concentrations (0.02 M‐0.14 M) have been determined at 298.15 K using magnetic float densitometer technique. Then apparent molar volumes ΦV of the electrolytes in above solvent mixtures were calculated. The apparent molar volumes of transfer ∆ΦV° (tr) were also calculated and the ion‐ion / ion‐ solvent interactions are then discussed on the basis of changes in the Masson′s slope and apparent molar volumes of transfer data.
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