Abstract

Tafel polarization method was used to assess the corrosion inhibitive and adsorption behaviours of amino-tris(methylenephosphonic) acid (ATMP) for C38 carbon steel in 1 M HCl solution in the temperature range from 30 to . It was shown that the corrosion inhibition efficiency was found to increase with increase in ATMP concentration but decreased with temperature, which is suggestive of physical adsorption mechanism. The adsorption of the ATMP onto the C38 steel surface was found to follow Langmuir adsorption isotherm model. The corrosion inhibition mechanism was further corroborated by the values of kinetic and thermodynamic parameters obtained from the experimental data.

Highlights

  • Corrosion inhibition of steel in acid solutions by different types of inhibitors has been extensively studied

  • It was shown that the corrosion inhibition efficiency was found to increase with increase in ATMP concentration but decreased with temperature, which is suggestive of physical adsorption mechanism

  • We have found that this compound is efficient inhibitor in 1 M HCl and the corrosion inhibition is mainly controlled by a physisorption process

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Summary

Introduction

Corrosion inhibition of steel in acid solutions by different types of inhibitors has been extensively studied. Tafel polarization method was used to assess the corrosion inhibitive and adsorption behaviours of aminotris(methylenephosphonic) acid (ATMP) for C38 carbon steel in 1 M HCl solution in the temperature range from 30 to 60◦C.

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