Abstract
Complexes of ruthenium(III) with the following beta-diketones: 2,4-pentanedione (Ru(acac)3), 1,1,1-tri- fluoro-2,4-pentanedione (Ru(tfac)3), 2,2,6,6-tetramethyl-3, 5-heptanedione (Ru(thd)3), 2,2,6,6-tetramethyl-4-fluoro- 3,5-heptanedione (Ru(tfhd)3) and 1,1,1-trifluoro-5,5-dime- thyl-2,4-hexanedione (Ru(ptac)3) were synthesized and identified by means of mass spectrometry. By effusion Knudsen method with mass spectrometric registration of gas phase composition the temperature dependencies of satu- rated vapor pressure were measured for ruthenium(III) compounds and the thermodynamic characteristics of vaporization processes enthalpy DHT* and entropy DS oof
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