Study of synergetic effect of the complex polycarboxylate anti-corrosion additive in the model of pore concrete fluid

Abstract

Introduction. Corrosion of reinforcement in concrete structures is rather expensive for the economy of any country. Current statutory documents offer two main directions — primary and secondary protection. One of the promising areas of primary protection methods is the use of complex anti-corrosion additives in concrete due to its technological simplicity and economic efficiency. Passivators and surfactants (SAS), as components of such additives, are of particular interest. Sodium nitrite is offered as a passivator, and polycarboxylate molecules (PCE) — as a SAS. The additive of sodium nitrite together with PCE has a visual synergistic effect. Materials and methods. Identification of structural characteristics of the molecules of the obtained PCE polymers was determined by methods of exclusion gel-permeation chromatography and 13C NMR spectroscopy. To study the synergetic effect of NaNO2 + PCE additive, the samples were kept in the models of pore liquid, after which the morphology of their surface was studied by methods of scanning electron microscopy and electron probe microanalysis. Results. The texture and surface color of the presented micrographs indicate surface formations on the samples stored in the models of pore liquid with different anti-corrosion additives. Electron probe microanalysis showed increased concentrations of carbon, oxygen and sodium on the surface of samples stored in pore concrete liquid models with the addition of a complex anti-corrosion additive of sodium nitrite and PCE, which indicates increased concentrations of PCE and possible increased pH on the steel surface. Based on the data acquired, the mechanism of formation of a protective film layer using complex anti-corrosion additive NaNO2 + PCE is offered. Conclusions. Justification of synergetic effect of complex polycarboxylate anti-corrosion additive in the model of concrete pore liquid opens up prospects for research of such additives to the concrete model.