Abstract
The infrared, Mössbauer, and 1H, 13C and 119 Sn NMR spectra have been used to study the structure of bis(triphenylstannyl) chromate(VI) in solid state and in solvents of both noncoordinating and coordinating types. In solid state the compound forms a three-dimensional polymer: the tetrahedral CrO4 group and trans-trigonally bipyramidal (C6H5)3SnO2 grouping are connected mutually symmetrically by bridges represented by the common oxygen atoms. The three phenyl groups in the (C6H5)3SnO2 grouping are located in the equatorial plane of the trigonal bipyramide which is completed by two bridge oxygen atoms in axial positions. Solutions in noncoordinating solvents contain monomeric bis(triphenylstannyl) chromate(VI). The ester molecule contain two tetrahedral, (C6H5)3SnO groups bound by oxygen bridges to a CrO4 group which shows the C2v symmetry. In coordinating solvents the title compound forms a molecular complex having the coordination number 5 at the central tin atom.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Collection of Czechoslovak Chemical Communications
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.