Study of Solidifying Surplus Sludge as Building Material Using Ordinary Portland Cement

Abstract

In an attempt to effectively utilize a multitude of surplus sludge from sewage treatment plants, ordinary Portland cement was used to solidify the dry surplus sludge as a building material. The dry surplus sludge and cement were mixed at different proportions with a certain dosage of water and then cured for 3–60 days at room temperature. The unconfined compression strength (RC) of solidified blocks was investigated with respect to the effects of the ratio of liquid to solid (Rl/S), surplus sludge dosage (DS), the dosage of sodium silicate (DNa2SiO3), and the proportion of fly ash (WF). The fabricated solidified blocks were characterized by scanning electron microscopy (SEM), Fourier transform-infrared spectroscopy (FT-IR), and X-ray Diffraction Analysis (XRD). The results demonstrated that RC at 60 days reduced obviously with the increase in Rl/s when Ds was given, whereas RC reduced with DS increased to 15.0 wt% from 5.0 wt% for solidified blocks. When DS was 5.0 wt%, RC of 28 days was reduced from 20.87 MPa to 14.50 MPa, with an increase in Rl/s from 0.35 to 0.55. For the given Rl/s, such as Rl/s = 0.35, RC at 60 days was 23.75 MPa, 2.80 MPa, and 2.50 MPa when DS were 5.0 wt%, 10.0 wt%, and 15.0 wt%, respectively, which were relatively lower in comparison to that of Portland cement solidified blocks without surplus sludge (51.40 MPa). In addition, the addition of Na2SiO3 and fly ash was favorable in terms of improving the RC for solidified blocks. RC of 60 days increased initially and then reduced with the increase in DNa2SiO3 from 0.0 wt% to 9.0 wt% at Rl/s = 0.45 and DS = 5.0 wt%. At DNa2SiO3 = 7.5 wt%, Rl/s = 0.45, and DS = 5.0 wt%, the highest RC value of 34.70 MPa was achieved after being cured for 60 days. Furthermore, RC of 60 days increased initially and then reduced with WF increasing from 0.0 wt% to 25.0 wt%, and the highest RC value of 34.35 MPa was achieved at WF = 10.0 wt%, Rl/s = 0.45, and DS = 5.0 wt%. At the ratio of DNa2SiO3 = 7.50 wt%, Rl/S = 0.35, WF = 20 wt%, DS = 15.0 wt% and M = 1.00, RC of 28 days reached 26.70 MPa. With these values, the utilization of sludge utilized (DS = 15.0 wt%) was increased by double compared with DS = 5.0 wt% (20.87 MPa). To investigate the effect of environmental temperature on the mechanical properties and mass of solidified blocks, the freeze-thaw cycling experiment was carried out. The RC of 28 days and the mass of the solidified block reduced with the number of freeze-thaw cycles, increasing for solidified blocks with DS of 5.0 wt%, 10.0 wt%, and 15.0 wt%, manifesting a decrease of 25.60%, 32.30%, and 40.60% for RC and 3.40%, 4.10%, and 4.90% for mass, respectively. This work provides sufficient evidence that surplus sludge has a huge potential application for building materials from the perspective of improving their mechanical properties. It provides an important theoretical basis for the disposal as well as efficient utilization of sludge.