Study of reaction of sulfur halides with unsaturated. Compounds. 24. Reaction of sulfur monochloride with adamantylidene-adamantane

Abstract

In the reaction of adamantylideneadamantane with S2Cl2 at an equimolar ratio of the reagents, 2,2′-epithio-2-(2′-adamantyl)adamantane and 4-chloro-2,2′-epithio-2-(2′-adamantyl)-adamantane are formed, while with an excess of S2Cl2, the products are 4e-chloro- and 4e,4′e-dichloroadamantylideneadamantane.