Abstract

The influence of two kinds of polymers (polystyrene (PS), acrylonitrile−styrene copolymer (SAN)) on the crystallization behavior of isotactic polypropylene (iPP) has been investigated by means of wide-angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC), and polarized optical microscopy (POM). The current experimental results indicated that these two kinds of polymers with low concentration, as special β-nucleating agents, can induce the β-iPP polymorph during quiescent melt crystallization. The nucleating activity of SAN or PS significantly depends on its concentration, molecular structure, and thermal history of processing. The content of β-crystal form increases with the increasing crystallization temperature or nucleating agent (SAN or PS) percentage, reaches a maximum value, and then decreases as the temperature or nucleating agent percentage further increases. Under the same crystallization condition, SAN is more effective than PS on inducing a higher level of β-crystal form in iP...

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