Study of photopolymer. XIX. Novel syntheses of the polymers with pendant ester and chloromethyl groups by addition reactions of the copolymer of glycidyl methacrylate with acid chlorides

Abstract

AbstractPolymer with pendant cinnamic ester and chloromethyl groups was synthesized by the addition reaction of poly(glycidyl methacrylate–co–methyl methacrylate) (PGMA) with cinnamoyl chloride. Also, polymers with pendant benzoic esters and chloromethyl groups were synthesized by reaction of PGMA with the corresponding benzoyl chlorides. Furthermore, polymers with cinnamic or benzoic esters and alkylazide groups were prepared by the substitution reaction of the obtained polymers with sodium azide.