Abstract

Several (Nb,Cr)N coatings were deposited by an unbalanced magnetron sputtering system. Following the deposition, the tribological properties of these coatings were studied using a ball-on-disk setup with alumina balls. The wear debris was then characterized using Raman spectroscopy to identify oxides generated during the wear process to gain a better understanding of tribochemical reactions. The results show that Cr 2O 3 and CrNbO 4 constitute the debris obtained from Cr-rich coatings, while Nb 2O 5· nH 2O is the major constituent of the debris formed on Nb-rich coatings. From the study of the debris, the difference in wear mechanism between Cr-rich and Nb-rich coatings is explained and confirmed.

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