Study of optical characteristics of microdischarges in the micro-arc oxidation process

Abstract

Micro-arc oxide coatings of aluminum alloy AD31 samples were formed in an electrolyte containing 2 g/l NaOH and 9 g/l Na2SiO3 for 2, 4, 8, 16 min in the anode and anode-cathode modes. During the processing, the forming curve, the time dependences of the charge passed through the galvanic cell, and the optical parameters of the microdischarges were measured using the optical synchronization method developed by the authors with subsequent image recognition. The thickness of the coatings was measured using a point autofocus probe surface texture measuring instrument Mitaka PF-60, the surface morphology was studied using a VEGA3 scanning electron microscope using SBH surface topography. The elemental composition of the coatings was determined using a scanning electron microscope JSM-6610LV. The analysis of the elemental composition and morphology of the surface revealed that the inner layer of synthesized coatings consists of Al2O3, the outer layer consists of Al2O3·SiO2 mullite, and the ratio of phases Al2O3 and mullite changes with changes in current density and oxidation mode. The formation of mullite is due to the presence of Na2SiO3 in the electrolyte. It is shown that with increasing processing time and current density, the thickness, roughness and porosity of coatings increase. The interrelation of the optical parameters of microdischarges with the morphology of the surface and the elemental composition of the formed coatings is substantiated; it is shown that the ratio of illuminated and non-illuminated sections of the sample surface by microdischarges can be used as a rough estimate of the ratio of electron and ion currents corresponding to microplasma and electrochemical processes. A mathematical model describing the dependence of the coating thickness on the oxidation time based on Faraday's laws for electrolysis and the results of measuring the optical parameters of microdischarges and the electrical parameters of the MAO process without taking into account microplasma processes that do not lead to an increase in the thickness of coatings is proposed. The error of adequacy of the proposed model does not exceed ±10 %. The results of the study can be used in the development of a digital twin of the micro-arc oxidation process.