Abstract
Preparation of new organic composites by direct solid–solid charge-transfer reaction between bis(ethylenedioxy)tetrathiafulvalene (BO) and iodine is described. We present also dc electrical conductivity investigation of composites: (BO) x /I, where 0.5< x<1.5. In the best case, corresponding to x=1, a metallic behaviour is observed down to 200 K prior to any annealing stage with a room temperature conductivity as high as 12.8 S cm −1.
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