Abstract
According to the available data in the literature, an atom of phosphoryl oxygen serves as the main reaction center in molecules of neutral organophosphorus extractants during their coordination to electrophilic molecules and ions [i]. When complexes of stoichiometric ratio 2:1 or more are formed, oxygen molecules are assumed to be attached by a mechanism whereby the next molecule is joined to the preceding one (chain mechanism) [2], e.g., for MNO~
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