Abstract

Research results for methanol steam reforming and ethanol conversion in a conventional and a membrane reactor in the presence of Ru–Rh/DND, LiZr2(PO4)3, and Li1.1Zr1.9In0.1(PO4)3 catalysts have been described. The samples have been characterized by X-ray diffraction, scanning electron microscopy, and the BET method. The study of the catalytic properties of the catalyst composites has shown that the Ru–Rh/DND catalyst mostly mediates the dehydrogenation process, while LiZr2(PO4)3 and Li1.1Zr1.9In0.1(PO4)3 exhibit activity in both the dehydration and dehydrogenation reactions. The membrane process with a Pd–Ru alloy membrane provides a 20% increase in the hydrogen yield.

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