Study of Lower Tropospheric Ozone over Central and Eastern China: Comparison of Satellite Observation with Model Simulation

Abstract

The lower tropospheric ozone enhancement over Central and Eastern China (CEC) was reported by Hayashida et al. (Atmos Chem Phys 15(17):9865–9881, 2015) using the Ozone Monitoring Instrument (OMI) multiple-layer product retrieved by Liu et al. (Atmos Chem Phys 10(5):2521–2537, 2010), which first showed the lower tropospheric ozone enhancement from ultraviolet and visible (UV-Vis) spectra measurements from space. However, to clarify the enhancement in the concentration of the lowermost ozone using spaceborne measurements, it is necessary to understand the effect of ozone variation in the upper troposphere and lower stratosphere (UT/LS), because of large smoothing errors in the retrieval scheme. In this study, a scheme was developed to eliminate the artificial effect of UT/LS ozone enhancement on lower tropospheric ozone retrieval using OMI. By applying the UT/LS screening scheme for June 2006, we removed the artificial effect of the UT/LS ozone enhancement on the lower tropospheric ozone. Even after UT/LS screening, we were able to show a clear enhancement in the lower tropospheric ozone over CEC in June 2006 and confirmed the conclusion derived by Hayashida et al. (Atmos Chem Phys 15(17):9865–9881, 2015). To clarify the reason for ozone enhancement in June, the effects of emissions from open crop residue burning (OCRB) in the North China Plain on lower tropospheric ozone were also examined using a comparison with model simulations. On the scale of the vertical resolution of OMI observations, the effect of OCRB on ozone enhancement does not seem to be significant, although it may be more significant when focusing on ozone in the planetary boundary layer.