Abstract
AbstractA special method of electrodialysis has been developed for investigation of the kinetics and mechanism of polymerization reactions involving ions. The ionic composition of homogeneous systems such as Cp2TiRClAlRCl2, RTiCl3 + AlRCl2, Ti(OR)4 + AlR3, and (RLi)n has been studied. The composition of catalytically active ions has been determined. Using the regularities of “open” systems, the methods of determining the carbocation reactivity under electrodialysis conditions havebeen worked out. The impulse electrodialysis method has been suggested for studying ionic polymerization kinetics and evaluating the rate constants ofion reactions with the monomer and gegenion.
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