Study of intermolecular interactions through dielectric properties of the mixtures consisting of 1,4-butanediol, primary amyl alcohols and 1,4-dioxane at various temperatures

Abstract

This paper presents relative permittivities, excess permittivities, effective dipole moments, and excess Kirkwood correlation factors of binary mixtures of 1,4-butanediol with two primary pentanol isomers [1-pentanol (amyl alcohol)+3-methyl-1-butanol (isoamyl alcohol)] from T=(298.15 to 318.15)K at p=101.3kPa over the entire composition range. Experimental permittivity values for polar–non-polar binary systems of (1,4-dioxane+amyl alcohol or isoamyl alcohol) were also obtained as a function of composition at the same range of temperatures. The experimental permittivity data were fitted using Redlich–Kister equation to evaluate the adjustable parameters and the standard errors. From the experimental data, the excess parameters were calculated. In this work, variations of effective dipole moment and correlation factor were investigated using Kirkwood−Frohlich equation. The experimental data of measurements were used in the analysis of the homo- and hetero interactions occurring in these binary solutions.