Year-end Sale % OFF 
Abstract
[70]fullerene has been shown to form 1:1 EDA complex with anthracene, naphthalene, phenanthrene, pyrene and acenaphthene in CCl 4 medium. Charge transfer (CT) bands have been detected in all the cases. Isosbestic points have been observed in the cases of phenanthrene and acenaphthene complexes. Ionisation potentials of the donors and CT transition energies have been found to correlate in accordance with Mulliken equation and from this correlation the electron affinity of C 70 has been found to be 2.59 eV. Enthalpies and entropies of formation of the complexes have been estimated from the formation constants of the complexes determined spectrophotometrically at three different temperatures.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
