Study of grain boundary properties in Ag-clad Bi2Sr2Ca2Cu3Ox tapes by multi-phase electron backscatter diffraction analysis

Abstract

The properties of grain boundaries within Ag-clad (Pb,Bi)2Sr2Ca2Cu3Ox (Bi-2223) tapes are studied by means of electron backscatter diffraction (EBSD). The achieved high image quality of the Kikuchi patterns enables multi-phase EBSD scans including Bi-2223, Bi2Sr2CaCu2Ox (Bi-2212), Bi2Sr2CuOx (Bi-2201), (Sr,Ca)14Cu24O41 and Ag to be performed. For the EBSD scans a maximum spatial resolution of 30 nm was reached enabling a detailed orientation analysis. The nature of the grain boundaries is discussed on the base of the EBSD data. While the main orientation of the tape is in [0 0 1] direction, a large number of misorientations is detected. These misorientations are visualized using crystal direction (CD) maps. Furthermore, EBSD enables the spatially resolved mapping of the misorientation angles within each phase separately. The influence of these grain boundaries on the current transport properties is discussed.