Abstract
This work has carried out on grafted nanoparticles oxide silica to determine the possible existence of nanoeffect. The textural properties and heterogeneity of surface of the samples were studied at the interface solid-gas. The Geometric properties were discussed in terms of the surface area while the energy properties were discussed in terms of the reactive sites of the surface.In the framework of this study, firstly, the sample was used in the non-grafted state and then in the grafted state using a hydrophilic molecule and a hydrophobic molecule. Several techniques have been used: Infrared spectroscopy, X ray diffraction, the point by point volumetric technique, which enable us to study the interactions between the adsorbate and the solid surface. Finally we have determined the size and electro thermal mobility using zestasizer (Nano ZS). The results obtained show that there are two types of groups silanols and siloxanes on the silica OX5 giving a composite hydrophilic-hydrophobic. This character causes a singular behavior in adsorptive material, the presence of hydrophilic groups, strongly polarized, and is detected by infrared spectroscopy. These groups cause significant differences depending on the polarizability of the probe molecules, and the adsorption of argon shows no heterogeneity of the surface, while nitrogen is adsorbed on the polar sites at low relative pressure, While the volumetric continues to adsorption of argon and nitrogen on combustion silica to obtain and to highlight sites of high energy and polar surface sites. The combustion silica which has been used as adsorbent in this study has an amorphous surface, virtually free of impurities indicates that the sample is not micro porous and grafting of the molecules makes a decrease in high energy sites or to a relative increase in surface low energy. © 2013 The Authors. Published by Elsevier B.V. Selection and peer-review unde r responsibility of the Organizing Committee of CSM8-ISM5.
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