Abstract

Introduction: In recent years, in building materials science, there has been a tendency for the active introduction of hollow microspheres of various types for modifying the properties of building materials. Hollow microspheres are most widely used in the production of liquid thermal insulating coatings, which reduce heat loss, protect structures from corrosion and overheating, prevent condensation formation, reduce operating costs and increase the time between repairs. Aim: Assessment of the influence of the structural characteristics of granular systems on the properties of thermal insulating materials. Methods: It is proposed to determine and evaluate the structural characteristics of filler powders by the method of small-angle X-ray scattering. The most important feature of this method is analyzing the internal structure of disordered systems - particles, pore space, interfaces between heterogeneities of heterogeneous substances. When assessing thermal conductivity and thermal resistance, the stationary heat flux method was used following GOST 30290–94. The essence of the method is to create a stationary heat flux passing through a flat sample of a certain thickness and directed perpendicular to the front (largest) faces of the sample, measuring the density of this heat flux, the temperature of the opposite front faces and the thickness of the sample. Results and Discussion: The paper discusses the results of experimental studies that make it possible to create liquid thermal insulation coatings (LTIC) based on polymer binders, fine mineral powders, and a complex of modifying additives. Experimental studies of the structure and properties of heat-insulating coatings based on filled polymer binders confirm their superiority over foreign analogs. Conclusions: It has been established that during the production of LTIC, their heat-shielding properties can be regulated by changing: pressure, the viscosity of the molecular weight of the gas; porosity of macrostructure and clusters; the thermal conductivity of the solid and gas phase of the system; the coefficient of accommodation; coordination number; primary particle size; fractal dimension characterizing the topological features of the structure of particles, aggregates, globules, clusters and their tendency to dissipate the energy of gas molecules.

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