Abstract
The underpotential shift of adsorbed gold is about 0.06 V. Adatom deposition on a platinum surface may take place via ionization of the substrate metal. It may be assumed that during the oxidation of adsorbed gold, corrosion of the substrate metal catalysed by adsorbed gold also takes place. Contrary to earlier results, the number of hydrogen adsorption sites covered by one gold adatom is only about one.
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