Study of effectiveness of heavy metals ions as the inhibitors of steel corrosion

Tatiana Shabliy,Julia Nosachova,Valeriya Vember,Yaroslav Radovenchik

doi:10.15587/1729-4061.2017.106974

Abstract

The effect of ions of d-metals on the processes of corrosion in a movable and immovable neutral aqueous environment has been investigated. It was shown that a number of ions, such as zinc, chromium, lead, under conditions of high aeration and temperature of 20 oС at concentrations of 2−5 mg/dm3, are effective inhibitors of steel corrosion. This is due to the formation of a passivation oxygen film on the surface of metal. The degree of corrosion protection is maintained at the level of 80−90 %. In the case of elevating the temperature to 50 oС, a significant (up to 40 %) decrease in the inhibitory properties of ions of d-metals is observed. This is due both to the destabilization of the oxygen passivation film and the growth of oxidation rate of steel with increasing temperature. It was demonstrated that phosphonic acids, such as oxyethyldidiphosphone acid, nitrilotrimethylphosphonium acid, due to the interaction of complexons with the surface of metals, stabilize the passivation oxygen film, providing a degree of protection against corrosion at 95−98 % at acid dose of 10 mg/dm3. However, when the temperature rises to 50 °C, a protective effect is reduced. It was established that the use of compositions based on OEDPhA/NTMPhA and Zn/Pb/Cr ions in the range of temperatures 20−50 oC provides a degree of protection of steel from corrosion at the level of 90 %. This is explained by the formation of three-dimensional complexes of phosphonic acids with metal ions and corroded iron

Highlights

Corrosion causes significant economic losses as it leads to the failure of pipelines, parts of machines, boilers and other metal products
One of the major problems caused by corrosion is the loss of world metal reserves, which in turn leads to significant environmental damage inflicted by steel production
With an increase in the temperature of aqueous medium from 20 °C to 50 °C, the protective effect is reduced from 93 % to 59 % and from 81 % to 75 % for oxyethylidendiphosphonic acid (OEDPhA) and nitrilotrimethylphosphonic acid (NTMPhA), respectively, at a dose of 5 mg/dm3

Summary

Introduction

Corrosion causes significant economic losses as it leads to the failure of pipelines, parts of machines, boilers and other metal products. One of the major problems caused by corrosion is the loss of world metal reserves, which in turn leads to significant environmental damage inflicted by steel production. The amount of wastewater discharged from these systems to water reservoirs remains significant and makes up about 8−30 % of the system’s volume. This is mostly linked tp the sedimentation in water circulation systems and corrosion processes. One of the directions of the protection of closed watercircular systems from corrosion is the use of ions of heavy metals and inhibitors of scale formation

Literature review and problem statement

Research goal and objectives

Findings

Conclusions