Study of dynamic heterogeneity of an active particle system.

Abstract

We have studied spatial and temporal dynamic heterogeneity (DH) in a system of hard-sphere particles, subjected to active forces with constant amplitude and random direction determined by rotational diffusion with correlation time τ. We have used a variety of observables to characterize the DH behavior, including the deviation from standard Stokes-Einstein (SE) relation, a non-Gaussian parameter α_{2}(Δt) for the distribution of particle displacement within a certain time interval Δt, a four-point susceptibility χ_{4}(Δt,ΔL) for the correlation in dynamics between any two points in space separated by distance ΔL within some time window Δt, and a vector spatial-temporal correlation function S_{vec}(R,Δt) for vector displacements within time interval Δt of particle pairs originally separated by R. By mapping the particle motion into a continuous-time random walk with constant jump length, we can obtain the average waiting time 〈t_{x}〉∝D_{s}^{-1} and persistence time 〈t_{p}〉∝η, with D_{s} the self-diffusion coefficient and η the shear viscosity, such that the observable λ=〈t_{p}〉/〈t_{x}〉∝D_{s}η can be calculated as a function of the control parameter τ to show how it deviates from its SE value λ_{0}. Interestingly, we find λ/λ_{0} shows a nonmonotonic behavior for large volume fraction φ_{a}, wherein λ/λ_{0} undergoes a minimum at a certain intermediate value of τ, indicating that both small and large particle activity may lead to strong DH. Such a reentrance phenomenon is further demonstrated in terms of the non-Gaussian parameters α_{2}, four-point susceptibility χ_{4}, and vector spatiotemporal correlation functions S_{vec}, respectively. Detail analysis shows that it is the competition between the dual roles of particle activity, namely, activity-induced higher effective temperature and activity-induced clustering, that leads to such nontrivial nonmonotonic behaviors. In addition, we find that DH may also show a maximum level at an intermediate value of φ_{a} if τ is large enough, implying that a more crowded system may be less heterogeneous than a less crowded one for a system with high particle activity.