Abstract
The catalytic activity of copper chromite catalysts prepared by thermal decomposition reaction of basic copper(II) ammonium chromate, CuCrO4[Cu(OH)2]0.17−(NH4OH)0.78, and copper(II) chromate CuCrO4, has been studied. The catalysts with highly disordered structure, prepared from basic copper(II) ammonium chromate at 270–320 °C, show the highest catalytic activity in reductive alkylation reaction. The activity of recrystallized catalysts, prepared from basic copper(II) ammonium chromate or CuCrO4 at higher decomposition temperature, is significantly lower.
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