Abstract
The autoxidation of vitamin C has been studied in acetonitrile by electronic spectroscopy. Some interesting data on the role of acetonitrile in autoxidation have been obtained, perhaps for the first time. A parallelism between hydroxyl ions and CH2CN−, the ions from the self-ionization of acetonitrile, has been established. The CH2CN− anion is similar to hydroxyl anions in initiating and propagating the decomposition of ascorbic acid, at least in this system. The intermediates involved in the overall reaction in nonaqueous media have been identified by simple means.
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